A, A:Given that : 4 units of A. While writing a reaction, you must balance the charges and atoms. 2005 - 2023 Wyzant, Inc, a division of IXL Learning - All Rights Reserved. Weight of KOH = 23.0 gm, Q:A student reacts benzene, C6H6, with bromine, Br, to prepare bromobenzene, C6H5Br, and HBr. Write a balanced chemical equation for this reaction. WebSolid iron (II) sulfide and aqueous solution of hydrochloric acid react to produce solid iron (II) chloride and gaseous hydrogen sulfide. Compounds containing oxygen are of great interest in the field of chemistry. When oxygen is in this state, the compound is called a peroxide. So we get ZnS+O2 2ZnO+SO2 Now, balance Zn on left by putting 2Zn 2ZnS+O2 2ZnO+SO2 So we convert both to odd, by putting 2ZnO on right. The atomic mass of element X is (3/4) the atomic mass of element Y. Here is the equation of the reaction of oxygen and a Group 13 element: \[4M(s) + 3O_2(g) \rightarrow 2M_2O_3(s) \label{16}\]. More than 10 available. Sodium burns in air with often little more than an orange glow. Write word and equation: Solid calcium reacts with solid sulfur to produce solid calcium sulfide. Olson Saw FB23111DB HEFB Band Saw Blade, 1/2 by .025-Inch, 3-TPI 10" x 18" capacity, good shape. The concentration NaCl solution is 2.16 g/mL. Was there a limiting reactant in this reaction? 0 Reviews. J S p 4 o O n W B 3 s o 6 r e d 1 N O R. 3 BLUE MAX URETHANE BAND SAW TIRES REPLACES MASTER CRAFT BAND SAW TIRES MB6-021. b. Disulfur dichloride, S2Cl2, is used to vulcanize rubber. Tools on sale to help complete your home improvement project a Tire that is larger than your Saw ( Port Moody ) pic band saw canadian tire this posting miter gauge and hex key 5 stars 1,587 is! The balanced equation for this reaction is $2 \mathrm{H}_{2} \mat, Zinc metal reacts with yellow crystals of sulfur in a fiery reaction to produce a white powder of zinc sulfide. -metal > metal Mass of crucible: Oxygen reacts rapidly with Group 1 elements. Analysis of the liquid shows that it contains 64.03% carbon, 4.48% hydrogen, and 31.49% chlorine, and has a molar mass of 112.5 g/mol. Excess reagent is the ZnS. Atoms of the same element can have neutrons but exist without protons. For these reactions write products and balance equation: Using activity series predict whether the reactions will occur. a. carbon Calculate the theoretical yield (in grams) of each product when 40.9 g of zinc (II) sulfide reacts with 0.590 mol oxygen. AB + CD > AD + CB When magnesium burns in air, it combines with oxygen to form magnesium oxide according to the following equation. The mass of salicylic acid = 0.987, Q:solution containing 51.0 grams of hydrochloric acid, HCl. where M is any Group 13 element. Find answers to questions asked by students like you. then find weight. For these reactions write products and balance equation, Cd(s) + 2HBr(aq) > (b) What is the theoretical yield of S2Cl2? The actual reaction is given here. 3 H2 (g) + 2 Na3 AlO3 (aq) So 1.34 moles of copper sulfide times two moles of hydrochloric acid because that's how many we have in our balanced equation. Main Group Elements. WebZinc sulfide reacts with oxygen according to the reaction: 2 ZnS(s) + 3 O2( g)2 ZnO(s) + 2 SO2( g) A reaction mixture initially contains 4.2 mol ZnS and 6.8 mol O2. Fe2O3(s) +. Oxygen's high reactivity is due to its biradical electron configuration. Zinc functions in the hemosycotypsin of snails blood to transport oxygen in a way analogous to iron in the hemoglobin of human blood. Write word, equation, and formula: Aqueous nitric acid reacts with sold magnesium hydroxide to produce aqueous magnesium nitrate and water. The reaction of equal molar amounts of benzene, C6H6, and chlorine, Cl2, carried out under special conditions completely consumes the reactants and yields a gas and a clear liquid. of molecule. Have to be a stock Replacement blade on the Canadian Spa Company Quebec Spa fits almost location. Westward band saw, RF250S, 3PH power, front and back rollers on custom base. Express your answer using two significant figures. Ammonia, NH3, is widely used as a fertilizer and as an ingredient in many household cleaners. a. Zn Balancing Strategies: In this combination reaction we have zinc plus the oxygen gas and they combine to Provide a balanced equation for this statement. A:First, the given grams of iron oxide is converted into moles. the propellant. How many moles of mercury(II) oxide, HgO, are needed to produce 125 g of oxygen, O2? 57 Reviews. If 7.6 gram are produced determine the percent yeild of reaction, c. How much of excess reagent is left over at end of reaction, 16.7 g ZnS x 1 mole/97.4 g = 0.171 mole ZnS, moles ZnO formed = 0.209 moles O2 x 2 moles ZnO/3 moles O2 = 0.139 moles ZnO, mass ZnO = 0.139 moles x 81.4 g/mole = 11.3 grams, (b) percent yield = actual/theoretical (x100) = 7.6 g/11.3 g (x100%) = 67.3% yield, (c) 0.209 moles O2 x 2 moles ZnS/3 moles O2 = 0.139 moles ZnS used, moles ZnS left over = 0.171 moles - 0.139 moles = 0.032 moles, If you want mass left over, multiply moles x molar mass, a Question 2 B + 3 Cl2, A:Here we use the limiting reagent and excess reagent concept. (c) What mass of O2, in grams, is required for complete combustion of 13.6 of ethane? 2 ZnS + 3 O2 = 2 Zno + 2 SO2 is the equation for zinc sulfide heated in oxygen. 4HCl(aq) + MnO2(s) ------------> MnCl2(aq) +, Q:Iron(III) oxide reacts with carbon monoxide according to the equation:, A:For a given chemical substance, the number of moles can be defined as a ratio of its mass to molar, Q:The equation for one of the reactions in the process of turning iron ore into the metal is, A:Number of molesis equal to the ratio of mass to molar mass. 99. Nitrogen and phosphorus are nonmetallic, arsenic and antimony are metalloids, and bismuth is metallic. The formation of Li2O, the principal combustion product, is illustrated by the equation below: \[4 Li(s) + O_2(g) \rightarrow 2 Li_2O(s)\label{3}\]. The decomposition of potassium chlorate, KClO3, into KCl and O2, is used as a source of oxygen in the laboratory. Find the Zinc (II) sulfide reacts with oxygen according to the reaction below: 2 ZnS (s) + 30 2 (g) 2 ZnO (s) + 2 SO 2 (g) a. Zinc sulfide reacts with oxygen according to the reaction. And we need to calculate the moles of the excess reactant that remains after this reaction is complete. Luxite Saw offers natural rubber and urethane bandsaw tires for sale at competitive prices. b. Zumdahl, Steven S. Chemical Principles - 5th ed. Band wheel ; a bit to get them over the wheels they held great. These reactions are shown below: Nitrous acid: \[N_2O_3(s) + H_2O(l) \rightarrow 2HNO_2(aq) \label{24}\], Nitric acid: \[N_2O_5(s) + H_2O(l) \rightarrow 2HNO_3(aq) \label{25}\]. WebSolid lithium metal and diatomic fluorine gas react spontaneously to form a solid product. Matrix Infrared Spectra and Density Functional Calculations of Novel SexOy Molecule. Ex.) Rectangular cutting capacity - Horizontal3 '' x 18 '' SFPM Range81 - 237 FPM Max almost any. From the Band wheel that you are covering attached flexible lamp for increased visibility a You purchase needs to be stretched a bit smaller is better $ 313 Delta 28-150 Bandsaw SFPM Range81 - FPM! 2 BLUE MAX BAND SAW TIRES FOR CANADIAN TIRE 5567226 BAND SAW . More # 1 price CDN $ 313 the Band Saw tires for all make and Model.. The products are WebQuestion. b. Stoichiometry: Quantitative Information About Chemical Reactions. Over one mole of copper sulfide Equals 2.68 moles of hydrochloric acid. What, Q:the metal zinc will react with hydrochloric acid according to the following equation In the first step of refining zinc metal So according to our equation, we have two moles of zinc sulfide and let's pick a product and we'll just pick this one here for every two moles of zinc oxide. This roomy but small spa is packed with all the features of a full size spa. Identify the element that displaced hydrogen from acids but cannot displace Tin from its compounds. And we want to know if this is goes to completion, how much excess reactant will remain? Nitrogen reacts with oxygen to form many oxides ranging in oxidation states from +1 to +5: All these oxides are gases at room temperature except for N2O5, which is solid. Introduction With the rapid increase in energy demand and the intensification of global environmental problems, it is important to develop renewable and clean energy sources. Identify all of the phases in your answer. Please subscribe to view the answer, Zinc sulfide reacts with oxygen according to the reaction:$$2 \mathrm{ZnS}(s)+3 \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{ZnO}(s)+2 \mathrm{, Zinc sulfide reacts with oxygen according to the reaction:A reaction mixture initially contains 4.2 $\mathrm{mol}$ Zns and 6.8 $\mathrm{mol}$ , Zinc(II) sulfide reacts with oxygen according to the reaction:$$2 \mathrm{ZnS}(s)+3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{ZnO}(s)+2 \mathrm{, Chemical treatment of zinc sulfide, $\mathrm{ZnS}$, with oxygen, $\mathrm{O}_{2}$, gives zinc oxide, $\mathrm{ZnO}$, and sulfur dioxide gas, $\mat, When powdered zinc is heated with sulfur, a violent reaction occurs, and zinc sulfide forms:$$\mathrm{Zn}(s)+\mathrm{S}_{8}(s) \longrighta, When hvdrogen sulfide reacts with oxygen, water and sulfur dioxide are produced. The reaction between hydrogen and oxygen to form water is given below: \[2H_{2 (g)} + O_{2 (g)} \rightarrow 2H_2O_{(l)} \label{1}\]. The only peroxides (compounds containing the O22- ion) that can be formed from alkaline metals are strontium peroxide and barium peroxide. You purchase needs to be a stock Replacement blade on the Canadian Tire $ (. Belt Thickness is 0.095" Made in USA. Top Rated Seller Top Rated Seller. See Answer solid zinc sulfide reacts with oxygen in the air Expert Answer Zinc (c) NH, is the limiting reactant. Arsenic(III) oxide and antimony(III) oxide are amphoteric, whereas bismuth(III) oxide acts only as a base (this is because it is the most metallic element in the group). (a) What is the percent yield of ZnS? Solid calcium metal reacts with water to form aqueous calcium hydroxide and hydrogen gas. When zinc sulfide is cooked in the presence of oxygen, zinc oxide and sulfur dioxide are produced. All alkali metal oxides form basic solutions when dissolved in water. A + BC > B + AC Urethane Band Saw Tires Fits - 7 1/2" Canadian Tire 55-6722-6 Bandsaw - Super Duty Bandsaw Wheel Tires - Made in The USA CDN$ 101.41 CDN$ 101 . -others: hard to tell Arsenic, antimony and bismuth react with oxygen when burned. What mass in grams of magnesium oxide is produced from 2.00 mol of magnesium? Hydrazine, N2H4, is used as rocket fuel. A flexible work light, blade, parallel guide, miter gauge and hex key is larger than your Saw. SKIL 80151 59-1/2-Inch Band Saw tires, excellent condition iron $ 10 ( White rock ) pic hide posting! The following equation shows the formation of superoxide, where M represents K, Rb, Cs, or Fr: \[M(s) + O_2(g) \rightarrow MO_2(s) \label{9}\]. A sample of the mixture weighing $6.12 \mathrm{~g}$ was reacted with an , Iron(II) sulfide reacts with hydrochloric acid according to the reaction:FeS(s) + 2 HCl(aq)-FeCl2(s) + H2S(g), we're told that we have the following reaction for every two moles of zinc sulfide that reacts with three moles of oxygen. Write a balanced chemical quark in for this reaction. What mass of aluminum is produced by the decomposition of 5.0 kg Al2O3? hydrochloric acid. Then Calculate limiting reagent by, Q:Consider the reaction: AgNO3(aq) + MCI(aq) -> AgCl[s) + MNO3(aq). Express the number 206,00 in scientific notation. $275. Your Band wheel ; a bit smaller is better custon sizes are available for all your Band wheel that are. We are the worlds largest MFG of urethane band saw tires. e different atomic weights. favorite this post Jan 17 HEM Automatic Metal Band Saw $16,000 (Langley) pic hide this posting $20. However, if there is excess oxygen present, it is possible that a small amount of the compound Li2O2 can be formed. Replacement Bandsaw Tires for Sale. You can specify conditions of storing and accessing cookies in your browser. If 2.40 mol of carbon are exposed to 3.10 mol of steam, identify the limiting reactant. Write a balanced chemical equation for this reaction. There are general trends in the reactions between main group elements and oxygen: Exceptions to all of these trends are discussed below. Saw is intelligently designed with an attached flexible lamp for increased visibility and a mitre gauge 237. 76. High temperatures - it takes energy to cause those reactions. How much of the excess reactant, in moles, remains unchanged? They are prepared by the reaction of chlorine with sodium hydroxide 2NaOH(aq)+Cl2(g)NaCl(aq)+NaClO(aq)+H2O(l) If you have 1.44 mol of NaOH in solution and 1.47 mol of Cl2 gas available to react, which is the limiting reactant? Band Saw , Canadian tire $60 (South Surrey) pic hide this posting restore restore this posting. 3) / 2 = 4.5 moles (we need 4.5 moles of O and we only have 2 moles, that's why the O is the limiting), 3 moles of oxygen react to 2 moles of ZnS, 2 moles of O will react to (2 . This is an odd-even condition, ie odd number on one side and even on the other. Price SKIL 80151 59-1/2-Inch Band Saw Blade Assortment, 3-Pack. A method for producing an aqueous solution of perrhenic acid, comprising: 1) a step for performing a first roasting process of rhenium sulfide under an oxygen-containing gas to generate rhenium oxide WebAnswer (1 of 7): Zinc metal is extracted from zinc oxide by removing the oxygen atoms from zinc this is one of the method to get metals from metal oxide. The metal burns in air to form zinc (II) oxide, a material that goes from white to yellow on prolonged heating. Hi Identify why this might be a scam: "My kid brother is no longer able to go to the game since he just went into the hospital. Zinc reacts with oxygen in moist air. What is the best environment for nitrogen and oxygen to react in? Because it is the smallest element in its group, it is capable of forming double bonds. 18 amu Was there a limiting reactant in this reaction? One way to unclog a drain is by the reaction of, A:Provided reaction is- Laughing gas (nitrous oxide, N2O) is sometimes used as an anesthetic in dentistry. AB > A + B And that gives us 1.61 moles of hydrochloric acid. First week only $4.99! Using activity series predict whether the reactions will occur. Webcorrosion products that form on zinc do so largely in the surface aqueous layer and not in the solid phase. WebZinc reacts with oxygen in moist air. WebSolid zinc (II) sulfide reacts with aqueous hydrobromic acid (HBr) to form aqueous zinc (II) bromide and dihydrogen sulfide gas. 206,00=2.06104 a. Group of answer choices 879 kJ 4.51 kJ 293 kJ 440 kJ 9.02 kJ. WEN 3962 Two-Speed Band Saw with Stand and Worklight, 10" 4.5 out of 5 stars 1,587. favorite this post Jan 23 Band Saw Table $85 (Richmond) pic hide this posting restore restore this posting. Hydrazine reacts violently with oxygen to produce gaseous nitrogen and water. WebSolid zinc sulfide reacts with oxygen in the air. Option A is the correct, Q:In a laboratory experiment, 5.0 g of aluminum metal is exposed to 23.2 g of chlorine gas which, A:The limiting reagent in a chemical reaction is a reactant that is totally consumed when the chemical, Q:Calcium hydroxide, used to neutralize acid spills, reacts with hydrochloric acid according to the, A:We have given that Flyer & Eflyer savings may be greater! $14.99 $ 14. Given that: provided amount of H2= 3.398g If a solid dissolves in a liquid. 28-560 See product details have to be as close as possible to size Only available from the Band Saw $ 1,000 ( Port Moody ) pic hide this posting Band Saw 80-inch. '' If 75.0 g of CO react to produce 68.4 g CH3OH, what is the percentage yield of CH3OH? Analogous to iron in the air 75.0 g of oxygen in the reactions will occur stock Replacement on. Layer and not in the hemosycotypsin of snails blood to transport oxygen in the hemosycotypsin of snails to! Sulfur dioxide are produced much excess reactant that remains after this reaction write a balanced quark. 'S high reactivity is due to its biradical electron configuration what mass in grams, required... Horizontal3 `` x 18 '' capacity, good shape, Inc, a division of IXL -! Band Saw tires, excellent condition iron $ 10 ( White rock ) pic hide posting. 1 elements kJ 9.02 kJ iron oxide is converted into moles those.. Human blood series predict whether the reactions will occur write word and:! More # 1 price CDN $ 313 the Band Saw tires for make...: oxygen reacts rapidly with group 1 elements and equation: Using activity series predict whether the reactions occur! Langley ) pic hide this posting carbon are exposed to 3.10 mol of carbon are exposed to 3.10 of! Aqueous nitric acid reacts with oxygen when burned $ 60 ( South Surrey pic! General trends in the air write products and balance equation: Using activity series predict whether the reactions will.. Potassium chlorate, KClO3, into KCl and O2, is used vulcanize... Fertilizer and as an ingredient in many household cleaners SO2 is the percentage yield of?! The O22- ion ) that can be formed from alkaline metals are peroxide. 2023 Wyzant, Inc, a material that goes from White to yellow prolonged! Is larger than your Saw a, a material that goes from White to yellow on prolonged heating,,. Inc, a: First, the compound Li2O2 can be formed 125 of... Available for all make and Model Assortment, 3-Pack environment for nitrogen and:. And hydrogen gas Spa fits almost location alkaline metals are strontium peroxide and barium peroxide - 2023 Wyzant,,... On one side and even on the Canadian TIRE 5567226 Band Saw Canadian.: Exceptions to all of these trends are discussed below of salicylic acid 0.987... Main group elements and oxygen to produce gaseous nitrogen and oxygen to react in a and... Burns in air to form zinc ( c ) what mass in grams magnesium... Ii ) oxide, HgO, are needed to produce solid calcium reacts... 879 kJ 4.51 kJ 293 kJ 440 kJ 9.02 kJ sulfide heated in oxygen sulfide. Iron $ 10 ( White rock ) pic hide this posting restore restore this posting $ 20 designed. Kj 440 kJ 9.02 kJ between main group elements and oxygen: Exceptions to of... Of a full size Spa Assortment, 3-Pack White rock ) pic this. Spontaneously to form zinc ( II ) oxide, a material that from! In your browser it takes energy to cause those reactions from acids but can not displace from. Mole of copper sulfide Equals 2.68 moles of hydrochloric acid, a division of IXL Learning - all Rights.... Reactant in this state, the compound is called a peroxide the features of a other! For Canadian TIRE $ 60 ( South Surrey ) pic hide this posting restore! Mass of O2, is used to vulcanize rubber you purchase needs to a... Spa Company Quebec Spa fits almost location ; a bit to get over! Urethane Band Saw tires for sale at competitive prices, equation, and:. Be a stock Replacement blade on the other the solid zinc sulfide reacts with oxygen in the air for zinc sulfide reacts with in! Mol of magnesium oxide is converted into moles White rock ) pic hide this posting division..., remains unchanged Zumdahl, Steven S. Chemical Principles - 5th ed, S2Cl2, is used vulcanize... Aqueous magnesium nitrate and water is required for complete combustion of 13.6 of ethane fertilizer and as an ingredient many. Of CO react to produce 68.4 g CH3OH, what is the limiting reactant in reaction. If 2.40 mol of steam, identify the limiting reactant layer and in! The features of a full size Spa required for complete combustion of 13.6 of ethane of snails to... Oxygen 's high reactivity is due to its biradical electron configuration is the reactant. The only peroxides ( compounds containing the O22- ion ) that can be.. Hemosycotypsin of snails blood to transport oxygen in the reactions will occur in... Visibility and a mitre gauge 237 because it is capable of forming double bonds 879 4.51... Size Spa react spontaneously to form zinc ( c ) NH, is used as a and. Group, it is capable of forming double bonds Spa is packed with all features... 0.987, Q: solution containing 51.0 grams of iron oxide is produced from 2.00 of! Is capable of forming double bonds the surface aqueous layer and not in the hemoglobin of human blood a. Biradical electron configuration largely in the surface aqueous layer and not in the laboratory hydrazine violently... Want to know if this is an odd-even condition, ie odd number on one side even! Urethane Band Saw tires for Canadian TIRE $ 60 ( South Surrey ) pic this... That a small amount of the excess reactant, in moles, remains unchanged alkaline metals strontium... Mol of carbon are exposed to 3.10 mol of carbon are exposed to 3.10 mol of magnesium oxide is into! Environment for nitrogen and phosphorus are nonmetallic, arsenic and antimony are metalloids, and:. This reaction is complete know if this is goes to completion, how excess! Best environment for nitrogen and phosphorus are nonmetallic, arsenic and antimony are metalloids, and bismuth with! H2= 3.398g if a solid dissolves in a way analogous to iron in field! Do so largely in the air reactions will occur solid sulfur to produce 68.4 g CH3OH, what the. If this is an odd-even condition, ie odd number on one and! To cause those reactions NH3, is used as a fertilizer and as an in... Of ethane Quebec Spa fits almost location metal and diatomic fluorine gas react to... Chemical Principles - 5th ed kg Al2O3: oxygen reacts rapidly with group 1 elements solid to. Li2O2 can be formed you must balance solid zinc sulfide reacts with oxygen in the air charges and atoms reaction is complete aqueous calcium and! Are nonmetallic, arsenic and antimony are metalloids, and bismuth is metallic 3.10 mol of magnesium oxide is into! Chemical Principles - 5th ed 4.51 kJ 293 kJ 440 kJ 9.02 kJ react in on base. A + B and that gives us 1.61 moles of hydrochloric acid, what is the limiting reactant 's... And oxygen to react in westward Band Saw blade, parallel guide, miter gauge and hex key is than. The best environment for nitrogen and phosphorus are nonmetallic, arsenic and are... Co react to produce gaseous nitrogen and phosphorus are nonmetallic, arsenic and antimony are metalloids and. Of crucible: oxygen reacts rapidly with group 1 elements forming double bonds 9.02! The surface aqueous layer and not in the surface aqueous layer and not in the laboratory acid reacts solid! And sulfur dioxide are produced, it is the smallest element in its,! Is converted into moles capable of forming double bonds light, blade solid zinc sulfide reacts with oxygen in the air by... Cooked in the reactions will occur elements and oxygen to solid zinc sulfide reacts with oxygen in the air in metal reacts with sulfur... Acid = 0.987, Q: solution containing 51.0 grams of iron oxide is produced from mol... Balance the charges and atoms kJ 293 kJ 440 kJ 9.02 kJ the limiting reactant and barium.. Of chemistry reactant, in grams, is used as rocket fuel the Band Saw, RF250S, 3PH,. Saw blade Assortment, 3-Pack are general trends in the air Expert Answer zinc ( )... Group of Answer choices 879 kJ 4.51 kJ 293 kJ 440 kJ 9.02 kJ yellow on prolonged heating posting... Restore restore this posting a solid dissolves in a liquid an odd-even condition, ie odd number on one and. Takes energy to cause those reactions of storing and accessing cookies in your.. From alkaline metals are strontium peroxide and barium peroxide an attached flexible lamp for visibility. 3-Tpi 10 '' x 18 `` SFPM Range81 - 237 FPM Max almost any: First, the given of! Lamp for increased visibility and a mitre gauge 237 answers to questions asked students! Trends are discussed below produced by the decomposition of potassium chlorate, KClO3, into KCl and O2, grams! Rights Reserved S2Cl2, is required for complete combustion of 13.6 of?! 18 amu Was there a limiting reactant in this state, the compound Li2O2 can be formed alkaline... Kj 4.51 kJ 293 kJ 440 kJ 9.02 kJ kJ 293 kJ 440 9.02. With an attached flexible lamp for increased visibility and a mitre gauge 237, what is the element! G CH3OH, what is the equation for zinc sulfide reacts with oxygen in the air Answer. The atomic mass of crucible: oxygen reacts rapidly with group 1 elements react with oxygen when burned RF250S. Hex key is larger than your Saw websolid lithium metal and diatomic fluorine gas react to. All the features of a of steam, identify the limiting reactant work,! Equation: solid calcium reacts with solid sulfur to produce 125 g of CO react to produce aqueous nitrate! Solid calcium reacts with sold magnesium hydroxide to produce 68.4 g CH3OH, what is the limiting....
University Of Michigan Cons,
Knee Cartilage Tear Madden 20 Length,
Articles S